Create a subdomain depends on the HTTP Server administration tool.
If you are using a cPanel, see the tutorial video CP-04 that show how to defined a subdomain in cPanel and how to create a slave site with a subdomain.
www.jms2win.com/en/tutorial#jms12x-CP-04
If you directly manage the apache "httpd.conf" file the you have to create a virtualhost entry to declare the subdomain.
You can get inspired from the user manual chapter 3.2.4
Once you have defined the subdomain in your server then you must know the "document root" directory that you associated to the subdomain.
When you know the "document root", you can go in JMS Multisites "manage site" menu and create a slave site that has the "deploy folder" equal to the "document root" path.
I hope this will help you