Verify the tutorial video 16 that show you how to proceed.
The expected result is to have the MySQL table shared.
You can go in the "JMS Tool" menu and verify how the tables are created between the master and the slave site.
If you have a link (infinite symbol) between the master and the slave site "#__users" table then you should have the same info between the website.
What you are describing is that the table in the slave site is not a link but a physical table.
This is the reason why I suggest you to review the tutorial video 16 to help you see the expected result.
www.jms2win.com/en/tutorial#jms12x-16
If you have a physical copy of the "#__users" table and not a link, this mean that you didn't created the slave site using a JMS Template rule that enable the sharing between the website.
In this case, review the creation of the slave site and the video should also help you.