If you want to convert a slave site into a standlone website, you need to perform a backup of your master that you will restore somewhere to become you standalone slave site.
When you have the backup restore, you can uninstall JMS in this slave site (as now you have a copy of joomla).
After that, you can re-use the configuration.php file of you slave site and also the specific files like images, templates that you would have created.
For your information, we are finalizing JMS 1.3.x that includes facilities for the migration, upgrade and update of joomla. It works also with multiple sites and will provide tools to migrate from joomla 1.5 to 2.5.
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