First if you have defined domains or subdomain with specific directories for each website then the constant is event not required as you should be in the "document root" directory of your websites.
If you are sharing the same "document root" for different domain or subdomain then the "MULTISITES_ID" is the result of a computation when you have an exact matching with a domain name defined in the slave site.
When the domain does not match, this is the master website that is displayed.
So you probably not have defined the slave site correctly and you probably not spelled it correctly.
If you want that I have a look on your server, this is possible with our billable support that you can order at
www.jms2win.com/en/joomla-multisite?page...35&category_id=1